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Q.

Two moles of an ideal monoatomic gas is heated from 27°C  to 627°C , reversibly and isochorically. The entropy of the gas is

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a

increases by  2Rln3

b

increases by  3Rln3

c

decreases by  2Rln3

d

decreases by  3Rln3

answer is B.

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Detailed Solution

For reversible and isochoric process the entropy change of gas is given by,

ΔS=nCvlnT2T1

for monoatomic gas, Cv=32R

n=2 mole T1=27C=27+273=300KT2=627C=627+272=900KΔS=2×32Rln900300ΔS=3Rln3

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