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Q.

Two moles of an ideal monoatomic gas occupy a volume V at 27o C. The gas expands adiabatically to a volume 2V. Calculate (i) the final temperature of the gas and (ii) change in its internal energy. (given 22/3=1.59)

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a

(i)195K(ii)2.7kJ

b

(i)189K(ii)2.7kJ

c

(i)189K(ii)2.7kJ

d

(i)195K(ii)2.7kJ

answer is C.

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Detailed Solution

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For adiabatic process relation of temperature and volume is 

T2V2γ1=T1V1γ1T2(2V)2/3=300(V)2/3 For monoatomic gasses,γ=53T2=30022/3=189K Also, in adiabatic process,ΔQ=0,ΔU=ΔW or ΔU=nR(ΔT)γ1=2×32×253(300189)=2.7KJ

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