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Q.

Two moles of helium gas undergoes a cyclic process as shown in figure. Assuming the gas to be ideal. (R=253  J/mol Kand lln2=0.693). Then

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a

The net change in the internal energy during process ABCD is zero.

b

Work done during the process BC is 4620 J.

c

The total heat given to the system is 1155 J.

d

The net change in internal energy is positive during process ABC.

answer is A, B, C, D.

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Detailed Solution

As we know in a cyclic process, the change in heat energy or heat supplied to the gas is equal to the net work done by the gas. Here, AB is isobaric process. Hence, work done during this process from A to B is

      WAB=PVB-VA=nRTB-TA or   WAB=2×253×400-300=1666.66 J

Work done during isothermal process from B to C is

 WBC=nRTClnV2V1=nRTClnP1P2          =2×253×400ln2          =2×253×400×0.693=4620 J

Work done during isobaric process from C to D

WCD=nRTD-TC=2×253×300-400          =-1666.66 J

Work done during isothermal process from D to A

 WDA=nRTDlnPDPA           =nRTDln2          =-2×253×300×0.693          =-3465 J

Net work done =WAB+WBC+WCD+WDA

                        =1666.66+4620-1666.66-3465=1155 J

Now from first law of thermodynamics

Here Q=U+W  thus we have

U=0  Q=W=1152.3 J

So the heat given to the system is 1152.3 J As the gas returns to its original state, there is no change in internal energy.

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