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Q.

Two moles of NH3 when put into a previously evacuated vessel (one litre) partially dissociate into N2 and H2. If at equilibrium one mole of NH3 is present, the equilibrium constant is

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a

3/4 mol2  litre-2

b

27/64 mol2  litre-2

c

27/32 mol2  litre-2

d

27/1 mol2  litre-2

answer is D.

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Detailed Solution

             NH3       N2  +    3H2

initial        2               0            0

at equil.    1               1            3

K=N2 H23NH32=  1 × 331=27 

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