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Q.

Two moles of PCl5 were heated in a closed vessel of 2 L. At equilibrium 40% of PCl5 is dissociated into PCl3 and Cl2. The value of equilibrium constant is

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a

5.3

b

0.53

c

0.267

d

2.63

answer is B.

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Detailed Solution

PCl5a(1-x) PCl3ax+Cl2ax
a=2,x=0.4,V=2LPCl5=2(10.4)2=0.6molL1PCl3=Cl2=2×0.42=0.4molL1Kc=0.4×0.406=0.267

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