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Two organic compounds p and Q are with the molecular formula C₈H₈O. Both P and Q forms an orange red precipitate with 2,4-DNP. P gives yellow ppt on heating with I₂+NaOH but not Q. ‘P’ does not reduce Tollens, reagent but ‘Q’ reduces. Then the structures of P and Q are

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answer is C.

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Detailed Solution

(1) Both Aldehyds & ketones form orange Red PPt
(2) Carbonyl compounds which contain methyl ketonic group only give yellow PPt
(3) Only Aldehydes can reduces Tollen’s reagent but not ketones.

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