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Q.

Two samples of water A and B having concentrations 16.2 ppm of Ca(HCO3)2 and 13.9 ppm of CaCl2 respectively. Then

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a

Hardness is more in ‘B’ sample than in ‘A’

b

Hardness is more in ‘A’ sample than in ‘B’

c

Hardness is same in both cases

d

Hardness of 'A' is 1.25 times less than the hardness of 'B'.

answer is A, D.

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Detailed Solution

A = 16.2 g of Ca(HCO3)2
B = 13.6 g of CaCl2
hardness of A (molar mass of Ca(HCO3)2 is 162 g/mol) = 16.2 x 100162=10 ppm
hardness of B  (molar mass of CaCl2 is 111 g/mol) =  13.9 x 100111=12.5 ppm

hardness of Bhardness of A=12.5 ppm10 ppm=1.25

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