Q.

Two solid compounds X and Y dissociates at a certain temperature as follows 
 X(s)A(g)+2B(g);   KP1=9×103  atm3 Y(s)2B(g)+C(g);    KP2=4.5×103  atm3
 The total pressure of gases over a mixture of X and Y is P atmosphere then find the value of 4P? (Take nearest integer)

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answer is 2.

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Detailed Solution

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Let x is partial pressure of A and y is partial pressure of C when both equilibrium simultaneously established in a vessel
  X(s)A(g)x   +   2B(g)(2x+2y);                                                                         KP1=PA.PB2(total) Y(s)C(g)x   +  2B(g)(2y+2x);                                                                           KP2=PC.PB(total)2
  KP1KP2=xyx=2y KP1=x(2x+2y)2    x=0.1atm;    y=0.05atm
   Total pressure of gases  =PA+PB+PC
  =3(x+y) =0.45 atm.

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Two solid compounds X and Y dissociates at a certain temperature as follows  X(s)⇌A(g)+2B(g);   KP1=9×10−3  atm3 Y(s)⇌2B(g)+C(g);    KP2=4.5×10−3  atm3 The total pressure of gases over a mixture of X and Y is P atmosphere then find the value of 4P? (Take nearest integer)