Q.

Two solids dissociate as follows  As   Bg+Cg;Kp1='x' atm2Ds   Cg+Eg;Kp2='y' atm2

The total pressure when the solids dissociate simultaneously is?

 

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a

x+y12 atm

b

x2+y2 atm

c

2x+y12 atm

d

x+y atm

answer is C.

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Detailed Solution

AsBgP1+CgP1+P2                                                KP1=x     atm2DsCgP1+P2+EgP2                                              KP2=y     atm2kP1=x=PB.PC,Similary,kP2=y=PC.PEx=P1P1+P2                                                                           ....1y=P2P1+P2                                                                         .....2Adding1and2x+y=P1+P22or  P1+P2=x+y                                                           ....3Totalpressure  Pt=PB+PC+PE=P1+P1+P2+P2=2P1+P2                                       Pt=2x+y  atmfrom3

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