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Q.

Two solutions containing non-volatile solutes 'P' and 'Q'  are prepared, with a molar mass ratio of MP:MQ=1:3. When these solutions are combined to create two final solutions X and Y with same mass of solute. Molar ratio of P & Q is 2:3 and 3:2, in 
X & Y respectively. What will be the ratio of elevation in boiling point for X to Y? (Assume no reaction between P, Q and water)
 

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a

4 : 7

b

2 : 3 

c

9 : 11  

d

3 : 2

answer is C.

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Detailed Solution

Average molecular mass of solute in X is  M(X)=2×MP+3MQ2+3=115MP
Average molecular mass of solute in Y is  M(Y)=3MP+2MQ2+3=95MP
 ΔTb(X):ΔTb(Y)=M(Y):M(X)=9:11

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