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Q.

Two spherical soap bubbles in vacuum are connected through a narrow tube. Radius of left bubble is R0  and that of right bubble is 2R0. Air flows from one side to another very slowly maintaining spherical shape of bubbles . At any instant before steady state is reached,  r1,  A1,  V1,  n1 are radius, surface area, volume and number of moles of gas in the left bubble and  r2,  A2,  V2,  n2 are radius, surface area, volume and number of moles in the right bubble. Assume that temperature T remains constant throughout the process. Let  n1=2 initially and S be the surface tension of soap solution. Choose the correct option(s). (R is universal gas constant)

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a

If, at an instant number of moles in left bubble is 1, then r1=R02

b

The total film area of both the bubbles is 15RTS

c

If, at an instant number of moles in left bubble is 1, then r2=3R02

d

Air flows from right to left bubble

answer is C, D.

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Detailed Solution

At any instant the total number of moles  n1+n2=n remains constant

 Also, n1n2=P1V1P2V2=4Sr1×43πr134Sr2×43πr23=r1r22=14n1+n2=2+8=10=constantP1V1+P2V2=nRT4Sr1×43πr13+4Sr2×43πr23=10RTA1+A2=7.5RTS=TotalSurfaceAreaisconstant When, n1=1n2=9r1r22=19r2=3r1; Also, since, totalsurfaceareaisconstant Initialsurfacearea=Finalsurfacearea4πR02+4π4R02 =4πr12+4πr22r12+r22=R02+4R02=5R02r12=110×5R02r1=R02r2=3R02

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