Q.

Two substances A t1/2=5 min and B t1/2=15 min are taken in such a way that initially [A]= 4[B]. Th time after which both the concentrations will be equal is : (Assume that reaction is first order)

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a

5 min

b

20 min

c

Concentration can never he equal

d

15 min

answer is B.

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Detailed Solution

For the given substance,

[A]t=[B]t

[A]0ek1t=[B]0ek2t4=ek1k2tt=2ln2ln25ln215=15 minutes 

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