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Q.

Two systems, PCl5(g)PCl3(g)+Cl2(g) and COCl2(g)CO(g)+Cl2(g)  are simultaneously in equilibrium in a vessel at constant volume. If some CO is introduced into the vessel, then at the new equilibrium, the concentration of  

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a

PCl5  is greater than that before

b

PCl3  is greater than that before

c

PCl5 is less than that before

d

COCl2 is more than that before

answer is B, C, D.

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Detailed Solution

 CO is added 2nd equilibrium shifts left
COCl2 is more than before Cl2  is reduced,
1st equation shift to the right
PCl5 will decrease 

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