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Two systems, ${PCl}_{5 (g)} ⇌ {PCl}_{3 (g)} + {Cl}_{2 (g)} and {COCl}_{2 (g)} ⇌ {CO}_{(g)} + {Cl}_{2 (g)}$ are simultaneously in equilibrium in a vessel at constant volume. If some CO is introduced into the vessel, then at the new equilibrium, the concentration of

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${PCl}_{5}$ is greater than that before

${PCl}_{3}$ is greater than that before

${PCl}_{5}$ is less than that before

${COCl}_{2}$ is more than that before

answer is B, C, D.

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Detailed Solution

CO is added 2^ndequilibrium shifts left
$∴$ ${COCl}_{2}$ is more than before ${Cl}_{2}$ is reduced,
$∴ 1^{st}$ equation shift to the right
$∴ {PCl}_{5}$ will decrease

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