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Q.

Two thermally insulated vessels 1 and 2 are filled with air at temperature (T1  ,T2) ,volume (V1  ,V2) and pressure (P1  ,P2) respectively. If the valve joining the two vessel is opened , the temperature  inside the vessel at equilibrium will be

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a

T1+T2/2

b

T1T2P1V1+P2V2/P1V1T2+P2V2T1

c

T1,T2

d

T1T2P1V1+P2V2/P1V1T1+P2V2T2

answer is C.

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Detailed Solution

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n=n1+n2P1V1+P2V2RTmx=P1V1RT1+P2V2RT2Tmix =T1T2P1V1+P2V2P1V1T2+P2V2T1

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