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Q.

Two unimolecular reactions, I and II, have the same rate constant at 25° C but Ea for reaction I is larger than Ea for reaction II. Which statement about these two reactions is correct?

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a

kreaction I is larger than kreaction II at lower temperatures but smaller at higher temperatures.

b

kreaction I is larger than kreaction II at temperatures both lower and higher than 25° C.

c

kreaction I is the same as kreaction II at all temperatures.

d

kreaction I is smaller than kreaction II at lower temperatures but larger at higher temperatures.

answer is C.

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Detailed Solution

lnk2k1=EaR1T11T2lnk2k1=EaR1T11T2

If Ea>Ea

 k2k1>k2k1

If T2>T1

or k2k1<k2k1

If T2<T1

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