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Q.

Type of hybridization and structure of complex $Fe {(CO)}_{5}$ is

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a

$d_{z^{2}} {sp}^{3}, trigonal bi pyramidal$

b

${sp}^{3} d_{x^{2} - y^{2}}, sq, pyramidal$

c

$d_{x^{2} - y^{2}} {sp}^{3}, sq, pyramidal$

d

None

answer is A.

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Detailed Solution

The hybridization is as follows : ₂₆Fe=1s²,2s²2p⁶,3s²3p⁶3d⁶4s²)
In Fe(CO)₅, the Fe-atom is

Solution Image

$∴ Trigonal bypyramidal$

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