Type of isomerism exhibited by compounds CrH2O6]Cl3,CrH2O5Cl]Cl2·H2O,CrH2O4Cl2Cl.2H2O and the value of coordination number (CN) of central metal ion in all these compounds, respectively is :

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Q.

Type of isomerism exhibited by compounds $[Cr {(H_{2} O)}_{6}] {Cl}_{3}, [Cr {(H_{2} O)}_{5} Cl] {Cl}_{2} \cdot H_{2} O,$ $[Cr {(H_{2} O)}_{4} {Cl}_{2}] Cl . 2 H_{2} O$ and the value of coordination number (CN) of central metal ion in all these compounds, respectively is :

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a

Geometrical isomerism, CN=2

b

Optical isomerism, CN=4

c

Ionisation isomerism, CN=4

d

Solvate isomerism, CN=6

answer is D.

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Detailed Solution

Isomers are differing in number of H₂O ligands; representing solvate isomer
C.N of central atoms = 6

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Type of isomerism exhibited by compounds CrH2O6]Cl3,CrH2O5Cl]Cl2·H2O,CrH2O4Cl2Cl.2H2O and the value of coordination number (CN) of central metal ion in all these compounds, respectively is :