Q.

 Type of isomerism Pair of examples
A)Ionisationi)PtNH33Cl2PtCl4 & PtNH32Cll2
B)Linkageii)CrNH36Co(CN)6 & CoNH36Cr(CN)6
C)Coordinationiii)CoNH35NO2Cl2 & CoNH35(ONO)Cl2
D)Polymerisationiv)CoSO4NH35Br & Co(Br)NH35SO4
 ABCD
1iiiiiiiv
2iiiiviii
3iviiiiii
4iviiiiii

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a

1

b

2

c

3

d

4

answer is C.

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Detailed Solution

two compounds having the same elemental composition but different molecular weights is called Polymerization isomerism 

Polymerization _ PtNH33Cl2PtCl4 & PtNH32Cll2

In a coordination isomer the total ratio of ligand to metal remains the same, but the ligands attached to a specific metal ion change

Coordination _ CrNH36Co(CN)6 & CoNH36Cr(CN)6

linkage isomerism or ambidentate isomerism is a form of isomerism in which certain coordination compounds have the same composition but differ in their metal atom's connectivity to a ligand

Linkage_  CoNH35NO2Cl2 & CoNH35(ONO)Cl2

The compound which give different ions in the solution, although they have same composition, are called ionization isomers and this property is known as ionization isomerism.

Ionization _ CoSO4NH35Br & Co(Br)NH35SO4

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