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Q.

Under identical conditions of temperature and pressure, the ratio of the rates of effusion of O2 and CO2 gases is given by:

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a

rate of effusion of oxygenrate of effusion of CO2=1.17

b

rate of effusion of oxygenrate of effusion of CO2=0.87

c

rate of effusion of oxygenrate of effusion of CO2=0.117

d

rate of effusion of oxygenrate of effusion of CO2=8.7

answer is B.

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Detailed Solution

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Temperature and pressure are constant

Molar mass of oxygen =(2×16)g/mole

Molar mass of carbon dioxide=44g/mole

Now,

According to graham's law of diffusion

Rate of diffusion is inversely proportional to the square root of molar mass

r α 1M r1r2=M2M1 r1r2=4432=1.17

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