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Q.

Under normal conditions ethene doesnot show addition reaction when it reacts with 

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a

Cl2/CCl4

b

Br2/CCl4

c

I2/CCl4

d

H2/Pt

answer is C.

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Detailed Solution

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Under normal conditions, ethene does not show an addition reaction with I2/CCl4.

 

Ethene is an unsaturated hydrocarbon with a double bond, which makes it reactive in many addition reactions. However, the reactivity of ethene depends on the reagent used. Commonly, ethene reacts easily with halogens like chlorine (Cl2) and bromine (Br2) in the presence of carbon tetrachloride (CCl4). These reactions lead to the formation of dihaloalkanes.

For example:

  • Ethene + Cl2/CCl4 → 1,2-dichloroethane
  • Ethene + Br2/CCl4 → 1,2-dibromoethane

 

Ethene also reacts with hydrogen (H2) in the presence of a catalyst such as platinum (Pt), forming ethane in a hydrogenation reaction. These are fast and well-known addition reactions.

In the case of iodine (I2) dissolved in carbon tetrachloride, the reaction is not favorable under normal conditions. Iodine is less reactive compared to chlorine and bromine, and its addition to ethene does not occur readily. Therefore, ethene does not show an addition reaction with I2/CCl4.

Correct Option

c) I2/CCl4

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