Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?
I. Acetyl chloride/pyridine followed by reaction with conc. H₂SO₄ + conc. HNO₃ .
Il. Acetic anhydride/pyridine followed by conc. H₂SO₄ +conc. HNO₃.
III. Dil. HCI followed by reaction with conc. H₂SO₄ + conc. HNO₃.
IV. Reaction with conc. HNO₃ + conc .H₂SO₄.

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I and II

III and IV

I and IV

II and III

answer is A.

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Detailed Solution

Aniline gives p - nitro derivative as the major product by
I. acetyl chloride/pyridine by reaction with conc. H₂SO₄ and conc. HNO₃.
II. acetic anhydride/pyridine followed by conc. H₂SO₄ and conc. HNO₃.

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