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Q.

Under which of the following reaction conditions, aniline gives p-nitro derivative as the major product?
I. Acetyl chloride/pyridine followed by reaction with conc. H2SO4 + conc. HNO3 .
Il. Acetic anhydride/pyridine followed by conc. H2SO4 +conc. HNO3.
III. Dil. HCI followed by reaction with conc. H2SO4 + conc. HNO3.
IV. Reaction with conc. HNO3 + conc .H2SO4.

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a

I and II

b

III and IV

c

I and IV

d

II and III

answer is A.

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Detailed Solution

Aniline gives p - nitro derivative as the major product by
I. acetyl chloride/pyridine by reaction with conc. H2SO4 and conc. HNO3.
II. acetic anhydride/pyridine followed by conc. H2SO4  and conc. HNO3.
 

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