Q.

Urea and phosphoric acid undergo H-bonding in the following manner :

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x1,x2 are H-bond length

y1,y2 are covalent bond length Select the only incorrect option :

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a

y2>y1

b

θ1<θ2

c

Number of pπdπ bonds present in the diagram is one

d

x1<x2

answer is C.

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Detailed Solution

The order of the bond angle is, θ1<θ2

In general, the C=O. bond length reduces as the OO hydrogen-bond length grows as the C-O(H) bond length increases. For larger O O distances, these changes become less noticeable. As the O O separation increases, the angles O=C-O(H) and C-C-O(H) get smaller, whilst the C-C=O increases.

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