Q.

Using the bond dissociation enthalpies (BDE) in the table, estimate ΔH for the disproportionation of hydrazine described in the equation below:

3N2H4(g)4NH3(g)+N2(g)

BondBDE,kJmol1BondBDE,kJmol1
NN163NN944
N=N409N-H388

 

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a

283 kJ×mol1

b

393kJ×mol1

c

455kJ×mol1

d

+283kJ×mol1

answer is D.

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Detailed Solution

Change in enthalpy

3×[163+4×388]12×388944=ΔHΔH=455kJ/mol

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Using the bond dissociation enthalpies (BDE) in the table, estimate ΔH∘ for the disproportionation of hydrazine described in the equation below:3N2H4(g)⟶4NH3(g)+N2(g)BondBDE,kJ⋅mol−1BondBDE,kJ⋅mol−1N−N163N≡N944N=N409N-H388