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Q.

Using the data given below find out the strongest reducing agent
$E_{C r_{2} O_{7}^{2 -} / C r^{3 +}}^{0} = 1.33 V$ $E_{C l_{2} / C l^{-}}^{0} = 1.36 V$
$E_{M n O_{4}^{-} / M n^{2 +}}^{0} = 1.51 V$ $E_{C r^{3 +} / C r}^{0} = - 0.74 V$

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a

Cl^-

b

Cr³⁺

c

Mn²⁺

d

Cr

answer is B.

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Detailed Solution

Chromium has low SRP. So its acts as strongest reducing.

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Using the data given below find out the strongest reducing agent ECr2O72−/Cr3+0=1.33V ECl2/Cl−0=1.36V EMnO4−/Mn2+0=1.51V ECr3+/Cr0=−0.74V