Using valence bond theory, explain the following in relation to the complexes given below [Co (NH3)6 ]3+(a) Type of hybridization(b) Inner (or) outer orbital complex. (c) Spin only magnetic moment value.

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Using valence bond theory, explain the following in relation to the complexes given below [Co (NH₃)₆ ]³⁺
(a) Type of hybridization
(b) Inner (or) outer orbital complex.
(c) Spin only magnetic moment value.

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Detailed Solution

(a) d²sp³

(b) [Co (NH₃)₆]³⁺ is an inner orbital complex as (n-1) d orbital is involved.

(c) Spin-only magnetic moment value is zero
$μ - \sqrt{n (n + 2)} - \sqrt{0 (0 + 2)} = 0 (Zero)$

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