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Q.

Usually chemisorption is favourable at

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a

low temperature and low pressure

b

low temperature and high pressure

c

high temperature and low pressure

d

high temperature and high pressure

answer is C.

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Detailed Solution

  • If the accumulation of gas on the surface of a solid occurs on account of weak van der Waals’ forces, the adsorption is termed as physical adsorption or physisorption.
     
  • When the gas molecules or atoms are held to the solid surface by chemical bonds, the adsorption is termed chemical adsorption or chemisorption.
     
  • A physical adsorption at low temperature may pass into chemisorption as the temperature is increased.
     
  • As the temperature increases, the conditions become favourable for Chemisorption and thus by LeChatelier's principle, high pressure favours chemisorption.
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