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Q.

V litre decinormal solution of NaCl is prepared. Half of the solution is converted into centinormal and added to the left decinormal solution. Then

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a

Normality of the final solution becomes 0.01 N

b

Number of millimoles of NaCl are reduced by

c

Molarity of the final solution becomes 0.018 M

d

Number of milliequivalents of NaCl do not change

answer is B, D.

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Detailed Solution

Given: Initial volume = V ; Normality = N10
Equivalents =V×110=V10
50% solution is taken
Vα×110=V×1100V=100×V20=5V
Final volume = (5V)
Now there are two solutions
I solution (Left solution) V2;N10
II-Prepared solution      5V;N100
 On mixing
N=N1V1+N2V2V1+V2=V20+V20/V2+5VN=V10×211V=2110=0.018N=0.018M
And no. of equivalent does not change on dilution.

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V litre decinormal solution of NaCl is prepared. Half of the solution is converted into centinormal and added to the left decinormal solution. Then