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Q.

van der Waals' constant ‘a’ in atm dm6 mol-2 and ‘b’ in dm3 mol-1 for some gases are

gasab x 102
Ar1.33.2
Ne0.21.7
Kr5.11.0
Xe4.15.0

which gas is expected to have highest critical temperature ?

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a

Ar

b

Ne

c

Xe

d

Kr

answer is C.

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Detailed Solution

Tc=8a27RbHighest 'a' and lowest 'b' gives highest Tc

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van der Waals' constant ‘a’ in atm dm6 mol-2 and ‘b’ in dm3 mol-1 for some gases aregasab x 102Ar1.33.2Ne0.21.7Kr5.11.0Xe4.15.0which gas is expected to have highest critical temperature ?