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van der Waal's constants for gases A,B and C are as follows:
Which of the following options contain correct arrangement of "gas with highest critical temperature" and "gas with most ideal behavior around 1850 K" respectively?

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B,A

A, B

C, B

B. C

answer is A.

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Detailed Solution

$\begin{matrix} T_{C} = 8 a / 27 R b \\ A & 548 \\ B & 1462 \\ C & 6857 \end{matrix}$ $\frac{8}{27} \times 1850 ≃ 548$

Hence, Boyle's temperature of A is closed to 1850 K

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