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Q.

Vander Waal’s equation for a gas is stated as 
 p=nRTVnba(nV)2
The equation reduced to the perfect gas equation, p=nRTV    when, 
 

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a

Temperature is sufficiently high, and pressure is low.

b

Both temperature, and pressure are very low.

c

Temperature is sufficiently low, and pressure is high.

d

Both temperature, and pressure are very high.

answer is A.

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Detailed Solution

(P+av2)v=RT   pv+avv2=RT     pv+av=RT    pv=RTav Divide with RT   PVRT=RTRTaRTV  Z=1aRTV

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