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Q.

Van't Hoff factor of 80% dissociated uni-trivalent electrolyte solution is

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a

3.6

b

3.25

c

3.75

d

3.4

answer is D.

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Detailed Solution

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They all are classified as ‘A3B’ type(uni-trivalent) electrolytes…..A3B 3A++B3- ; n=4

Examples….M3PO4

                     Van't Hoff factor, i = 1-α+ ;

    when n= 4

                    Van't Hoff factor, i = 1+3α ; 

i = 1 + 3(0.8)=3.4

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Van't Hoff factor of 80% dissociated uni-trivalent electrolyte solution is