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Q.

Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of the metal is

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a

21

b

54

c

27.06

d

2.086

answer is C.

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Detailed Solution

 Let wt. of metal oxide = 100 g

wt. of metal = 53 g

wt. of oxygen = 47 g

Equivalent weight of oxygen

                                        =wt.  of  metalwt.of  oxygen×8=5347×  8=9.02Valency=2×  V.DE+35.5  =  2×  669+35.5=13244.5=2.96=3

   Atomic weight = Equivalent weight x Valency

                                        = 9.20 x 3 = 27.06

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