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Q.

Vapour pressure of CCl4 at 25oC is 143 mm of Hg 0.5 gm of a non-volatile solute (mol. wt.=65) is dissolved in 100 mlCCl4. Find the vapour pressure of the solution: (Density of CCl4 = 1.58 g / cm2)

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a

199.34 mm

b

141.43 mm

c

143.99 mm

d

94.39 mm

answer is A.

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Detailed Solution

P0-PsP0=w×MmW=143-0.5×15465×158×143 =143-1.03=141.97 mm.

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