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Q.

Vapour pressure of solution containing 2 mol of liquid A (PA = 80 torr ) and 3 mot of liquid B (PB = 100 torr ) is 87 torr. We can conclude that

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a

there is negative deviation from Raoult's law

b

boiling point is higher than that expected for ideal solution

c

molecular attractions between unlike molecules are stronger than those between like molecules

d

all of these statements are correct

answer is D.

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Detailed Solution

For ideal solution vapour pressure of solution
=PAxA+PBxB=80×25+100×35=92 torr 
Since observed vapour pressure of solution < ideal vapour pressure, the solution shows negative deviation.

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