Q.

Vapour pressure of water decreases from one atmosphere to one bar by dissolving glucose. 
(1 atm = 1.01 bar). Which statement(s) is(are) correct ? (Pbar = 1atm).

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a

The solution contains approximately 1% of glucose by moles

b

The external pressure must be reduced by nearly 1% to boil the solution

c

The solution is nearly 9% w/w

d

The prepared solution boils at 100°C

answer is A, B, C.

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Detailed Solution

P0PP0=XB;XB=(1.01)1.01=0.011.01=0.0099nAnB=10.00991nAnB=10.00990.0099=100nBnA=1100=0.011% solute by moles nBnA=1 mole 100 moles nB=1 mole WB=180 gm  nA=100 mole WA=1800gmwt2 of glucose =1801800+180×100=180×1001980=9.09%

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