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Q.

Variation of equilibrium constant K for the reaction; 2A(s)+B(g) C(g)+2D(g) is plotted against absolute temperature T in figure as lnKVs(1/T) :

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a

Adding 'A' favours forward reaction

b

The forward reaction is endothermic

c

The slope of line is proportional to the magnitude of enthalpy of reaction

d

The forward reaction is exothermic

answer is A, C.

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Detailed Solution

The relation between Equilibrium constant and Temperature is given by Van't Hoff  equation, ln Keq=ΔH°RT+ΔS°R.

For the ln Keqvs1Tplot,ΔH°R is the slope.

The graph suggests positive slope, hence ΔH°R is positive or ΔH° is negative.Hence, the reaction is exothermic. Slope line is proportional to ΔH Also, by Le Chatelier's principle, removing C favours forward reaction.

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