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Q.

Variation of molar specific heat capacity at constant volume (CV) is shown as function of temperature  T for a diatomic gas. If for a certain amount of the considered gas internal energy in state C is 14 times the sum of internal energies in states A and B, find x.

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answer is 106.

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Detailed Solution

In states A, B and C degree of freedom are experimentally deduced to be fA=3, fB=5, fC=7 , respectively.
 As internal energy, U=f2nRT,
 Therefore internal energies in the three states are equal to
   UA=32nRT0             .....(i)UB=52nR(10T0)      .....(ii)UC=72nR(xT0)        ......(iii)
 It is given that, UC=14(UA+UB)
   72nR(xT0)=14[32nRT0+52nR(10T0)]
    `[using Eqs. (i), (ii) and (iii)]
    x=106
 

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