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Q.

Volume of strong mono basic acid of normality 10 is needed to prepare 1L of a buffer solution of pH9, using 1 mole of NH3 is”X” ml. Find X16
Kb for NH3=1.8×105;pKb=4.7447

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answer is 4.

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Detailed Solution

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NH4Cl is a salt of S.A-W.B
Since W.B (NH3) is left and NH4Cl is formed. So a mixture of W. Base & Salt is formed Which is a basic buffer.
                       NH3+HClNH4Cl Initial                                1x0 Final                               1x x xpOH=14pHpOH=149=5pOH =pkb+log10[ salt ][ base ]5=4.7447+log10x1x54.7447=log10x1xx=0.64N1V1=0.64V1=0.64N10.6410=0.064L=64ml=XX16=4 

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