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Q.

Volume of 0.01 M KMnO4 required to oxidise 2.88 gm of FeC2O4 in acidic medium.

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a

1.2 ml

b

600 ml

c

1200 ml

d

1000 ml

answer is C.

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Detailed Solution

KMnO4xf = 5  + FeC2O4xf = 3  Fe+2 + CO2 + Mn+2 eKMnO4 = eFeC2O4              M.wt.FeC2O4= 56 + 24 + 64 = 144 0.01×V×51000=2.881443  ;  0.01×V×51000=3×2100 ;  V =60005= 1200 ml

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