Q.

Water of mass m gram is slowly heated to increase the temperature from T1 to T2. The change in entropy of the water, given specific heat of water is 1 Jkg–1K–1, is :

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a

zero

b

m lnT2T1

c

m (T2–T1)

d

m lnT1T2

answer is D.

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Detailed Solution

The change in entropy (ΔS\Delta S) of water when it is heated slowly from temperature T1T_1 to T2T_2 can be found using the thermodynamic formula:

ΔS=T1T2dQT\Delta S = \int_{T_1}^{T_2} \frac{dQ}{T}

Since the heat added is:

dQ=mcdTdQ = mc \, dT

where:

  • mm = mass of water (in grams),
  • cc = specific heat capacity of water (11 J/g·K),
  • dTdT = small temperature change.

Substituting dQdQ into the entropy formula:

ΔS=T1T2mcdTT\Delta S = \int_{T_1}^{T_2} \frac{mc \, dT}{T}

Since mm and cc are constants, they come out of the integral:

ΔS=mcT1T2dTT\Delta S = mc \int_{T_1}^{T_2} \frac{dT}{T}

 ΔS=mcln(T2T1)\Delta S = mc \ln \left(\frac{T_2}{T_1} \right)

Final Answer:

ΔS=mcln(T2T1)\Delta S = mc \ln \left(\frac{T_2}{T_1} \right)

Since the specific heat of water is given as 1 J/g·K, we substitute c=1c = 1:

ΔS=mln(T2T1) J/K\Delta S = m \ln \left(\frac{T_2}{T_1} \right) \quad \text{J/K}

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