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Q.

What are interhalogen compounds? Give some examples to illustrate the definition. How are they classified?

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Detailed Solution

Interhalogen compounds: Halogens react with each other forming binary compounds known as inter halogen compounds.
Cl2+F2Δ2ClFCl2+3F2Δ2ClF3
Ex : ClF,ClF3,IF7 etc
Structural Aspect: In the compounds central halogen atom shows different hybridised states depends upon the bonding.
 

S.No.TypeExamplesElectronic stateHybridizationShape and structure
1AXClF,BrF,ICl
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sp3linear, A-X
2AX3ClF3,BrF3,ICl3 etc 
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sp3dTrigonal bipyramidal with 2 lone pairs (or) T-shape 
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3AX5ClF5,BrF5,IF5 etc 
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sp3d2Octahedral with one lone pair (or) square pyramidal
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4AX7IF7
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sp3d3Pentagonal bipyramid structure
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