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Q.

What are the reagent and reaction conditions used for converting ethyl chloride to ethyl nitrite (as the major product) ?

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a

${KNO}_{2}, C_{2} H_{5} OH, H_{2} O, Δ$

b

$KCN, H_{2} O, Δ$

c

${NaNO}_{2}, HCl, O^{0} C$

d

${AgNO}_{2}, C_{2} H_{5} OH, H_{2} O, Δ$

answer is A.

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Detailed Solution

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Potassium nitrite converts ethyl chloride into ethyl nitrite.

$C_{2} H_{5} Cl + {KNO}_{2} \to_{∆}^{C_{2} H_{5} OH} \underset{ethyl nitrite}{C_{2} H_{5} ONO}$

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