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Q.

What electronic transition in Li2+  produces the radiation of the same wavelength as the first line in the Lyman series of Hydrogen

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a

n = 9 to n = 3

b

n = 4 to n = 2

c

n = 9 to n = 6 

d

n = 6 to n = 3

answer is D.

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Detailed Solution

1λ=Rz21n12-1n22 for Li, z=3 1λ=32R1n12-1n22---1 for H, z=1, first line of Lyman series 1λ=R112-122---2 By 1 & 2, 32R1n12-1n22=R112-122 first line of Lyman series 1st line n1=1              n2=2 In Li2+ electronic transition,  6th level is same as 2nd level in H-atom  & 3rd level as first. So, n=6 to n=3

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