Q.

What fraction of Fe exists as Fe(III) in  Fe0.96O ? (Consider Fe0.96O  to be made up of Fe(II) and Fe{III) only)

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a

120

b

116

c

0.08

d

112

answer is B.

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Detailed Solution

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Fe0.96O

Let Fe(II) present in Fe0.96O = x

Fe (III) present = (0.96-x)

Total charge on Fe=2x+(0.96-x)3

Total charge on O = -2

2x + (0.96-x) 3 =2

2x +2.88 – 3x =2

-x = -0.88

x= 0.88

Fe2+=0.88,Fe3+=0.08

Fraction of Fe3+=0.080.96=112

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