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Q.

What happens when solid CuCN is dissolved in aqueous solution of KCN?

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a

[Cu(CN)4]3  is formed

b

(CN)2  is formed

c

Depression in  freezing point of solution  increases

d

[Cu(CN)4]2 is formed

answer is A, C.

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Detailed Solution

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CuCN  is in soluble on addition of KCN  complex is formed so number of ions increases depression in freezing point increases  

CuCN(S)  +3KCN(aq)K3[Cu(CN)4](aq)

Cu(CN)S+3K(aq)++3CN(aq)6​ moles3K(aq)++[Cu(CN)4](aq)34moles

ΔTfα number of particles of solute 

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What happens when solid CuCN is dissolved in aqueous solution of KCN?