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Q.

What is half life (t1/2) of a reaction? Derive the equation for the half life value of zero and first order reaction

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Detailed Solution

The time required for completion of half of the concentration of reactant is known as half life (t1/2)
For first order k=2.303tloga(ax)
k=2.303t1/2logaa/2
a = initial concentration of reactant
=2.303t1/2log102 if t=t1/2, ax=a/2=2.303t1/2×0.3010 k=0.693t1/2
For zero order k=xt
Since if t=t1/2, x=a/2
k=a2xt1/2,k=a2×t1/2,t1/2=a2k

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