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Q.

What is Lanthanide contraction? what are the consequences of lanthanide contraction?

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Detailed Solution

The steady decrease in atomic or ionic radii in lanthanides is called lanthanide contraction.
Reason: Poor shielding effect of 4f-subshell
Consequences of lanthanide contraction:
1) Due to lanthanide contraction the covalent nature of La-OH bond increases from La to Lu
2) Due to lanthanide contraction, the basic character of oxides and hydroxides decreases from La(OH)3 to Lu(OH)3
3) Due to lanthanide contraction, second and third transition series elements are almost similar size so it is very difficult to separate pair of elements

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