Q.

What is metallic corrosion ? Explain it with respect to Iron corrosion

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Detailed Solution

The spontaneous destruction of a metal due to its interaction with environment is called metallic corrosion corrosion of Iron is called rusting. At a particular spot of Iron, oxidation takes place, and the spot behaves as anode. anode: 2Fe2Fe+++4e¯
The released e s move to another spot of the Iron and reduce oxygen in the presence of H+ ions and this spot behaves as cathode
Cathode: O2+4H++4e¯2H2O
overall reacn =
2Fe+O2+4H+2Fe+++2H2O
Ferrous (Fe++) ions are further oxidized to ferric (Fe+++) ions by oxygen which come out as rust in the form of hydrated ferric oxide (Fe2O3 .xH2O)

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