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What is radioactivity? State the law of radioactive decay. Show that radioactive decay is exponential in nature.
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Detailed Solution
Radioactivity: Spontaneous decay of naturally occurring unstable nuclei by emission of certain sub-particles (like ,, and radiation) is called natural radioactivity.
By radioactivity process of emitting these rays nucleus tries to attain the stability.
Law of radioactivity: According to Rutherford and Soddy, the rate of decay or the number of nuclei decay per unit time at any instant is directly proportional to the number of nuclei (N) present at that instant and is independent of the external physical conditions like temperature, pressure, chemical composition etc.
Let ‘N’ be the number of radioactive atoms present at a time ‘t’ and ‘N0’ is the initial number of radioactive nuclei. Let ‘dN’ atoms disintegrate in time ‘dt’.
According to the law of radioactive decay
The proportionality constant ‘ ’is called decay constant or disintegration constant.
The negative sign indicates that as time increases ‘N’ decreases.
From equation (1)
On integration, we get
Here C is the constant of integration.
, substituting in equation (3),
we get
This shows that the number of nuclei decreases exponentially with time.