Q.

What is the correct electronic configuration of the central atom in K4[Fe(CN)6] based on crystal field theory ?

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a

eg4t2g2

b

t2g4eg2

c

t2g6eg0

d

eg3t2g3

answer is C.

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Detailed Solution

Configuration of  Fe+2 :  3d64s0

Configuration of K4[Fe(CN)6] : t2g6eg0

Since -CN is a strong field ligand, pairing takes place against to Hund's rule.

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